Download Ethers, Crown Ethers, Hydroxyl Groups and their Sulphur by Saul Patai PDF

By Saul Patai

Chapter 1 Synthesis of crown ethers and analogues (pages 1–57): Dale A. Laidler and J. Fraser Stoddart
Chapter 2 Crown ethers–complexes and selectivity (pages 59–156): Fritz Vogtle and Edwin Weber
Chapter three natural alterations mediated via macrocyclic multidentate ligands (pages 157–174): Charles L. Liotta
Chapter four Geometry of the ether, sulphide and hydroxyl teams and structural chemistry of macrocyclic and non?cyclic polyether compounds (pages 175–214): Israel Goldberg
Chapter five Stereodynamics of alcohols, ethers, thio ethers and comparable compounds (pages 215–278): C. Hackett Bushweller and Michael H. Gianni
Chapter 6 Chiroptical homes of alcohols, ethers, thio ethers and disulphides (pages 279–298): G. Gottarelli and B. Samori
Chapter 7 The mass spectra of ethers and sulphides (pages 299–325): Christian C. Van De Sande
Chapter eight The electrochemistry of ethers, hydroxyl teams and their sulphur analogues (pages 327–350): Tatsuya Shono
Chapter nine digital buildings and thermochemistry of phenols (pages 351–377): Jean Royer, man Bertholon, Robert Perrin, Roger Lamartine and Monique Perrin
Chapter 10 Syntheses and makes use of of isotopically labelled ethers and sulphides (pages 379–448): Mieczyslaw Zielinski
Chapter eleven Gas?phase thermal decompositions of easy alcohols, thiols and sulphides (pages 449–468): R. L. Failes, J. S. Shapiro and V. R. Stimson
Chapter 12 Oxidation and aid of alcohols and ethers (pages 469–538): Paul Muller
Chapter thirteen Oxidation and relief of sulphides (pages 539–608): Eric Block

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Extra resources for Ethers, Crown Ethers, Hydroxyl Groups and their Sulphur Analogues: Volume 1 (1981)

Example text

More recently, however, an acylationreduction sequence has afforded better overall yields of 11286 and related crown compounds7 >8 7 . Dale A. Laidler and J. Fraser Stoddart 24 7. Oxygen, nitrogen and sulphur systems Systems such as 114- 11 6 have been synthesized using ( a ) the alkylation app r o a ~ hand ~ ~( b ) the acylation-reduction sequence8 9 8 '. H 8. Crown Compounds Incorporating Aromatic Residues 1. g. 117 and 118, incorporating ortho-disubstituted benzene rings with both symmetrical and asymmetrical deployments around t h e polyether ring and with up to 9' qQnQp 0 0 0 O m (118) four aromatic rings fused to the macrocycle.

S . Bradshaw, R. A. Reeder, M. D. Thompson, E. D. Flanders, R. L. Carruth, R. M. Izatt and J. J. Christensen, J. Org. , 4 1, 134 (1 976). 85. D. St. C. Black and I. A. , 1055 (1970). 86. 3. -ivi. -P. Sauvage, Chem. , 1055 (1970). 87. D. Pelissard and R. Louis, Tetrahedron Letters, 4589 (1972). 88. D. E. Kime and J. K. Norymberski, J. Chern. ,Perkin I , 1048 (1977). 89. C. J. Pedersen,J. Org. , 36, 254 (1971). 90. S . Kopolow, T. E. I-Iogen Esch and J. Smid, Macromolecules, 6, 133 (1973); J. Smid, B.

G. 232-237, in which ( a ) ortho-disubstituted benzene rings have been incorporated' and ( b ) the ether oxygen atoms have been replaced progressively either ~~ X (233) (234) (235) (236) (237) Y Z NMe 0 0 NMe NMe 0 S S S 0 S S (2321 0 0 S by secondary and tertiary amine groups' or by sulphur atoms86. More recently, nzeta-xylyl, pyridyl, and I ,1 '-bipyridyl residues have been introduced into the side-arms. Finally, macrobicyclic polyethers have also been covalently bound' to a polystyrene support.

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